Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates.
نویسندگان
چکیده
Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols is achieved. A series of γ-ketophosphonates with different substituents were readily obtained. The mechanistic study indicated that the reaction was initiated by the addition of P-radicals, which sequentially undergo 1,2-migration of an aryl group to form C(Ar)-C(sp(3)) bonds.
منابع مشابه
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عنوان ژورنال:
- Organic & biomolecular chemistry
دوره 12 42 شماره
صفحات -
تاریخ انتشار 2014